Assessing Aluminum Concentration in Alum-Based Water Treatment Residuals in Halabja, Kurdistan Region of Iraq

Authors

  • Tareq Hamah-ameen Abdullah Sulaimani Polytechnic University, Halabja Technical Institute /Halabja, Medical Laboratory Technique, Kurdistan region of Iraq.

Keywords:

Aluminum residual, Alum, Alzheimer’s disease, Coagulation, Turbidity

Abstract

Background & Objectives: The use of alum in the water purification process increases
the residual aluminum content in water and potentially has adverse effects on people's health,
and considering the water source of Halabja city and the efficiency of the Halabja water
treatment plant in purifying or filtering aluminum concentration, this study aims to the study
of aluminum concentration in the drinking water treatment plant of Halabja, Iraq.
Method: In order to assessment of water, 3 sites were chosen for sample collection in the
study including raw water directly from Sirwan River, treated water from treatment plant and
tap water from households during the period from July to December 2023. Water samples were
collected in pre-cleaned, sterilized glass bottles of 500 ml capacity and transported to the
Atmosphere Company for Environmental and Laboratory Services in ice-cooled containers.
Analysis was done for chemical parameters including Aluminum (Al), pH, temperature (CO)
total dissolved solids (TDS), turbidity, and total Alkalinity.
Result: The amount of aluminum in Raw, Treated and Tap water was higher than the health
and healthy water standards. Although the amount of aluminum residuals in the treated water
was very low in the last analysis of sample, and despite being low, it was not in accordance
with international standards. Other physicochemical variables, pH, Turbidity, Temperature,
Alkalinity and T.D.S, although they were associated with fluctuations and increases in the
examined samples, but their values were in the optimal and standard range.
Conclusion: The use of alum in the purification process and the effect of other factors, the
concentration of aluminum remaining in the investigated waters is high and it is not safe and
sanitary water according to the standards, and this issue can have harmful effects on the
consumers of these waters.

References

Wondimu, M. (2016). Examining the impact of household access to water and sanitation on child malnutrition in

Ethiopia. https://doi.org/10.57709/8898819

Dassanayake, K. B., Jayasinghe, G. Y., Surapaneni, A., & Hetherington, C. (2015). A review on alum sludge reuse

with special reference to agricultural applications and future challenges. Waste Management, 38, 321-335.

https://doi.org/10.1016/j.wasman.2014.11.025

Srinivasan, P. T., Viraraghavan, T., & Subramanian, K. S. (1999). Aluminium in drinking water: An overview.

Water Sa, 25(1), 47-55.

Jones, K. C., & Bennett, B. G. (1986). Exposure of man to environmental aluminium—an exposure commitment

assessment. Science of the total environment, 52(1-2), 65-82. https://doi.org/10.1016/0048-9697(86)90105-1

Meghzili, B., Souad, B., & Abdelkrim, A. (2016). Risk of residual aluminum in treated waters with aluminum

sulphate. Advances in Research, 6(5), 1-8. https://doi.org/10.9734/AIR/2016/24059

Frommell, D. M., Feld, C. M., Snoeyink, V. L., Melcher, B., & Feizoulof, C. (2004). Aluminum residual control

using orthophosphate. Journal‐American Water Works Association, 96(9), 99-109. https://doi.org/10.1002/j.1551-

2004.tb10707.x

Nieboer, E., Gibson, B. L., Oxman, A. D., & Kramer, J. R. (1995). Health effects of aluminum: A critical review

with emphasis on aluminum in drinking water. Environmental Reviews, 3(1), 29-81. https://doi.org/10.1139/a95-002

Sollars, C. J., Bragg, S., Simpson, A. M., & Perry, R. (1989). Aluminium in European drinking water.

Environmental Technology, 10(2), 131-150. https://doi.org/10.1080/09593338909384727

Do, W. C. Y. (2017). Secondary Drinking Water Standards: Guidance for Nuisance Chemicals.

https://protectyourwater.net/files/2019/09/EPA-secondary-drinking-water-Regs.pdf

World Health Organization. (2004). Guidelines for drinking-water quality (Vol. 1). World Health Organization.

Alwan, L. L. (2018). Seasonal Variation of Residual Aluminum Concentration in Drinking Water. Engineering

and Technology Journal, 36(1 Part C), 63-70. https://doi.org/10.30684/etj.36.1C.10

Ward, M. K., Ellis, H. A., Feest, T. G., Parkinson, I. S., Kerr, D. N. S., Herrington, J., & Goode, G. L. (1978).

Osteomalacic dialysis osteodystrophy: Evidence for a water-borne aetiological agent, probably aluminium. The

Lancet, 311(8069), 841-845. https://doi.org/10.1016/S0140-6736(78)90191-5

Alfrey, A. C., LeGendre, G. R., & Kaehny, W. D. (1976). The dialysis encephalopathy syndrome: possible

aluminum intoxication. New England Journal of Medicine, 294(4), 184-188.

https://doi.org/10.1056/NEJM197601222940402

Flaten, T. P. (1990). Geographical associations between aluminium in drinking water and death rates with

dementia (including Alzheimer's disease), Parkinson's disease and amyotrophic lateral sclerosis in Norway.

Environmental Geochemistry and health, 12, 152-167. https://doi.org/10.1007/BF01734064

Neri, L., & Hewitt, D. (1991). Aluminium, Alzheimer's disease, and drinking water. The Lancet, 338(8763), 390.

https://doi.org/10.1016/0140-6736(91)90531-S

Niquette, P., Monette, F., Azzouz, A., & Hausler, R. (2004). Impacts of substituting aluminum-based coagulants

in drinking water treatment. Water Quality Research Journal, 39(3), 303-310. https://doi.org/10.2166/wqrj.2004.041

Rondeau, V., Commenges, D., Jacqmin-Gadda, H., & Dartigues, J. F. (2000). Relation between aluminum

concentrations in drinking water and Alzheimer's disease: an 8-year follow-up study. American journal of

epidemiology, 152(1), 59-66. https://doi.org/10.1093/aje/152.1.59

Klein, G. L., Alfrey, A. C., Miller, N. L., Sherrard, D. J., Hazlet, T. K., Ament, M. E., & Coburn, J. W. (1982).

Aluminum loading during total parenteral nutrition. The American Journal of Clinical Nutrition, 35(6), 1425-1429.

https://doi.org/10.1093/ajcn/35.6.1425

World Health Organization. (2003). Aluminium in drinking-water: background document for development of

WHO Guidelines for drinking-water quality (No. WHO/SDE/WSH/03.04/53). World Health Organization.

https://apps.who.int/iris/bitstream/handle/10665/75362/WHO_SDE_WSH_03.04_53_eng.pdf

Chao, H. J., Zhang, X., Wang, W., Li, D., Ren, Y., Kang, J., & Liu, D. (2020). Evaluation of

carboxymethylpullulan‐AlCl3 as a coagulant for water treatment: A case study with kaolin. Water Environment

Research, 92(2), 302-309. https://doi.org/10.1002/wer.1250

Costello, J. J. (1984). Postprecipitation in distribution systems. Journal‐American Water Works Association,

(11), 46-49. https://doi.org/10.1002/j.1551-8833.1984.tb05441.x

Kluczka, J., Zołotajkin, M., Ciba, J., & Staroń, M. (2017). Assessment of aluminum bioavailability in alum sludge

for agricultural utilization. Environmental monitoring and assessment, 189, 1-8. https://doi.org/10.1007/s10661-017-

-x

S. Agarwal, I. Tyagi, V.K. Gupta, M.H. Dehghani, R. Ghanbari, Investigating the residual aluminum elimination

from conventional and enhanced coagulation by phosphate compounds in wastewater treatment process, Journal of

Molecular Liquids, Volume 221, 2016, Pages 673-684, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2016.06.051

Mehdinejad MH, Alimohammadi N, Arbabmojeni S, Soltani A, Amanbaei A. Residual Aluminum from

application of Alum and Polyaluminum Chloride in removal of turbidity from turbid water. J Gorgan Univ Med Sci

; 16 (1) :82-88. URL: http://goums.ac.ir/journal/article-1-1978-en.html

Krupińska I. Aluminium Drinking Water Treatment Residuals and Their Toxic Impact on Human

Health. Molecules. 2020; 25(3):641. https://doi.org/10.3390/molecules25030641

Gaustad G, Olivetti E, Kirchain R. Improving aluminum recycling: A survey of sorting and impurity removal

technologies. Resources, Conservation and Recycling. 2012 Jan 1; 58:79-87.

Capuzzi S, Timelli G. Preparation and Melting of Scrap in Aluminum Recycling: A Review. Metals. 2018;

(4):249. https://doi.org/10.3390/met8040249

Abdel-Shafy, Hussein & Salem, Mohamed & El-Khateeb, Mohamed & Mansour, Mona & Abdel-Shafy, Nancy.

(2020). INNOVATIVE SYSTEM FOR RECYCLING OF BACKWASHING WATER IN DRINKING WATER

PLANT. Egyptian Journal of Chemistry. 63. 885-895. 10.21608/ejchem.2019.12186.1762.

Rodriguez AZ, Wang H, Hu L, Zhang Y, Xu P. Treatment of Produced Water in the Permian Basin for Hydraulic

Fracturing: Comparison of Different Coagulation Processes and Innovative Filter Media. Water. 2020; 12(3):770.

https://doi.org/10.3390/w12030770

Downloads

Published

2024-05-20

Issue

Section

Articles